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  WATER HARDNESS

Hardness is defined as the concentrations of calcium and magnesium ions expressed in terms of calcium carbonate, which can be calculated as shown in the equation:

Hardness mg/l = 2,5 [conc. Of Ca²+ (mg/l)] + 4,1 [conc. Of Mg²+ (mg/l)]

The most frequently used standard classifies water supplies is show in Table 1:

Hardness Concentration
Soft Water 0 to 17.1 mg/l (0 to 1 grain/gallon)
Slightly Hard Water 17.1 to 51.3 mg/l (1 to 3.5 grains/gallon)
Moderately Hard Water 51.3 to 119.7 mg/l (3.5 to 7 grains/gallon)
Hard Water 119.7 to 179.55 mg/l (7 to 10.5 grains/gallon)
Very Hard Water Over 179.55 mg/l (over 10.5 grains/gallon)

Table 1. Water Supply Classification

These minerals in water can cause some everyday problems. They react with soap and produce a deposit called "soap curd" that remains on the skin and clothes and, because it is insoluble and sticky, cannot be removed by rinsing. Soap curd changes the pH of the skin and may cause infection and irritation. It also remains on the hair making it dull and difficult to manage. Soap curd picks up the dirt from laundry water and holds it on cloth, contributing to a gray appearance of white clothes. It is especially troublesome when wash water is allowed to drain through the clothes. The use of synthetic detergents may help a little, but the active ingredient in the detergent is partially inactivated by hardness and more detergent must be used for the same cleaning task. Some detergents will produce soap during the reaction with oil or grease on the surface being cleaned and as a result they will also deposit soap curd. A ring around the bathtub and spotting on glassware, chrome and sinks are constant problems in the presence of hard water. They require additional rinsing and wiping, increasing the time spent on everyday cleaning.

Cooking with hard water can also be difficult, producing scale on pots. Some vegetables cooked in hard water lose colour and flavour. Beans and peas become tough and shriveled.

Hard water may also shorten the life of plumbing and water heaters. When water containing calcium carbonate is heated, a hard scale is formed that can plug pipes and coat heating elements. Scale is also a poor heat conductor. With increased deposits on the unit, heat is not transmitted to the water fast enough and overheating of the metal causes failure. Build-up of deposits will also reduce the efficiency of the heating unit, increasing the cost of fuel.

Most natural water supplies contain at least some hardness due to dissolved calcium and magnesium salts. Other minerals, such as iron, may contribute to the hardness of water, but in natural water they are generally present in insignificant quantities. The total hardness of water may range from trace amounts to hundreds of milligrams per liter.

Water Hardness Unit Definition
International recommended mmol/litre

100 mg CaCO3
per 1000 ml water

Physical measures mval/litre

28 mg CaO or 50mg CaCO3
per 1000 ml water

America & States PPM

1 part CaCO3
per million = 1 mg CaCO3
per 1000 ml water

English ºe

1 grain CaCO3
per gallon = 14,3 mg CaCO3
per 1000 ml water

French ºf

 
10 mg/CaCO3
per 1000 ml water

German ºdH

10 mg/CaO
per 1000 ml water

1 mmol/litre
1
2
100
7.0
10.00
5.6
1 mval/litre
0.5
1
50
3.5
5.00
2.8
1 PPM
0.01
0.02
1
0.070
0.10
0.056
1 ºe
0.1429
0.285
14.29
1
1.429
0.7999
1 ºf
0.10
0.20
10.00
0.700
1
0.5599
1 ºdh
0.1786
0.357
17.86
1.250
1.786
1

Table 2. Conversion of Water Hardness Units

WATER H2O HARDNESS

TEMPORARY HARDNESS: Ca and Mg BICARBONATES (precipitate minerals upon heating)
PERMANENT HARDNESS: Ca and Mg SULFATES OR CHLORIDES (dissolve with sodium)

 
DEGREE OF HARDNESS EXPRESSION

SOFT: LESS THAN 1,6 mmol/l = 160 PPM = 9 ºdH
SLIGHTLY HARD: 1,6-3,2 mmol/l = 160-320 PPM = 9-18 ºdH
HARD: 3,2-4,6 mmol/l = 320-460 PPM = 18-26 ºdH
VERY HARD: ABOVE 4,6 mmol/l = ABOVE 460 PPM = ABOVE 26 ºdH


 



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